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1、废旧银氢电池中镇的回收与利用黄家龙(辽宁石油化工大学,环境与生物工程学院,环境工程0502,抚顺，113001)摘要自从工业化以来金属锲氢电池在通讯效劳方面作为一种强大的资源.随着一些禁止的重金属(例如汞、铅、镉)增加,金属锲氢电池取代了大局部市场的铭-银电池.废金属银氢电池含有3342%的银、10%的钻和10%稀土元素,这些元素对于需要锲的市场是一个珍贵的来源.本文的重点是从废金属氢化物银电池(SMHB)中回收银和钻.论文中用到的电池所有都是产家给AB5型锲氢电池.其具体的实验方法是把正极和负极的电极材料破碎成直径为IPm的颗粒,然后对正极进行实验,通过正交试验确定酸的种类、酸的浓度、反响温
2、度、反响时间、固液比那个因素对溶解最有利,从而确定出最正确反响条件.之后在酸性条件下用无水硫酸钠沉淀稀土元素使其与银钻别离.然后对其过滤,在把滤液定溶于一定体积的容量瓶,通过丁二酮月亏分光光度法测定银含量；直接吸人火焰原子吸收法测定钻含量.而沉淀的硫酸稀土复盐用二乙三胺五乙酸(DTPA)滴定.最后考虑银钻的回收，由于银钻沉淀所需的PH不同，我们可以根据这个条件进行银钻的回收.银和钻的价态都是在二价的时候较为稳定,本文是采用碱沉淀和氧化沉淀往返收银钻,其沉淀物都是氢氧化物.通过实验研究分别对影响电池正锲在溶液中的浸出率的影响因素进行了析,对废旧氢-银电池电极材料中银元素在溶液中的浸出条件进行了优
3、化研究,并对废旧氢-锲电池电极材料中稀土元素、钻及银的回收提纯进行了分析研究,所得研究结果如下：本论文研究所用氢-银电池中银、钻元素在电池正极中所占百分比分别约为56%与60%,负极中银、钻及稀土元素分别占38.5%、7.11%与26%以上废旧氢-银电池混合电极材料在不同酸系中的银元素浸出率高于电极分开处理时的浸出率，这与电池正、负极组成物质有关,对稀土去除后的电极浸出液中滞留的钻元素分别采取了碱沉析出和氧化沉淀两种别离方法,通过比照分析发现,采用碱沉别离时,所得产品为Co()与Co(HI)氢氧化物的混合物,而用次氯酸钠为氧化剂在限制溶液PH=3.6时,可有效地氧化沉淀了废旧氢-锲电池电极材料
4、中的钻元素.关键字：废旧银氢电池,回收,银,沉淀Nickle-metalHydrideBatteriesUsedintheRecoveryandRseofNickelHuangJialong(1.iaoningShihuaUniversityiSchoolofEnvironmentalandBiologicalEngineering,EnvironmentalEngineering0502,1.iaoningFushun,113(X)1)AbstractMetalhydride-nickelbatteries(MHNB)wereusedasthepowersourceofportablecom
5、municationservicessincetheirindustrialization.Astheprohibitionofheavymetals(suchasmercury,leadandcadmium)increased,MHNBcantakeplaceofthemainmarketofcadmium-nickelbatteries.Spentmetal-hydride-nickelbatteriescontain33-42%nickeland10%cobaltand10%rareearthelements,theseelementsisavaluablesourceforthedem
6、andingmarketofnickel.Thefocusofthisarticleistherecoveryofnickelandrareearthfromspentnickelmetalhydridebattery(SMHB).AllthebatteriesusedintheP叩erarethatmanufacturersoffertheAB5-typenickel-hydrogenbatteries.Theirspecificexperimentalmethodisthepositiveelectrodeandnegativeelectrodematerialbrokenintopart
7、iclesofadiameteroflgm,Andthentoconductexperimentsonthecathode.Throughtheparalleltestdecidesthetypeofacid,acidconcentration,reactiontemperature,reactiontime,solid-liquidratioonthedissolutionofthemostbeneficialinordertodeterminetheoptimalreactionconditions.Inacidicconditions,usinganhydroussodiumsulfat
8、edepositsrareearthelementsinordertoletnickelandcobaltseparate.Thenfiltering.Determinedinthefillratedissolvedinacertainvolumeofvolumetricflask,determinationofnickelcontentbythespectrophotometricofdimethylglyoxime;determinationofcobaltcontentbydirectaspirationflameatomicabsorption.Andprecipitationofsu
9、lfatesaltsofrareearthcomplexistitratedwithDTPA(DTPA).Finally,consideringtherecoveryofnickelandcobalt,asnickelandcobaltprecipitationrequiredifferentpH,wecanbeinaccordancewiththetermsoftherecoveryofnickelandcobalt.Thevalencestateofnickelandcobaltarethemorestablewhentheirvalencestateare+2,thepaperisthe
10、useofalkaliandoxidationofsedimentstorecovernickelandcobaltprecipitation,anditssedimentsarehydroxides.Respectivelythroughtheexperimentalstudyoftheimpactofthebatterypositiveandnegativeelectrodematerialsandmixedmaterialsarenegativeinthesolutionofnickelintheleachingrateoffactoranalysisofusedhydrogen-nic
11、kelbalteryelectrodematerialsinnickelintheleachingsolutionconditionsResearchontheoptimizationoftheusedhydrogen-nickelbalteryelectrodematerialofrareearthelements,cobaltandnickelrecoveryfortheanalysisofpurified,obtainedresultsareasfollows:Inthispaper,theInstituteusedhydrogen-nickelbatteriesinnickel,cob
12、altcathodeelementsinthepercentageofcellswereabout56%and60%,negativeinthenickel,cobaltandrareearthelements,respectively,accountingfor38.5%,7.11%and26%ormore.Usedhydrogen-nickelbatteryelectrodematerialsformixedsystemsindifferentacidleachingofnickelhigherthantheelectrodeseparatedfromtheleachingrateatwh
13、ichthebatterypositiveandnegativeelectrodematerialformedontheelectrodeaftertheremovalofrareearthIeachingsolutionstrandedCobaltelementsweretakenalkaliprecipitationandoxidationoftwoseparationmethods.Bycomparingtheanalysisfoundthattheuseofalkali-precipitationseparation,theproductsderivedfromCo(II)andCo(
14、III)hydroxidemixture,UsingsodiumhypochloriteasoxidantinControlsolutionatpH=3.6,tobeeffectiveinoxidationofthewastehydrogenprecipitation-nickelbatteryelectrodematerialofthecobaltelement.KeywordsSpentmetalhydridebatteries.Recovery,Nickel,Precipitation.目录1文献综述51.1 银氢电池的开展前景51.2 电池失效的原因61.3 国内外对银氢废电池的研究现
15、状71.3 .1国外研究现状81.4 .2国内废旧电池回收现状91. 4废旧氢-银电池回收处理技术101.4. 1火法冶金处理技术111.4.2湿法冶金处理技术112实验局部132. 1实验药品及仪器132 .1.1实验仪器133 .1.2实验药品132. 2142. 2.1对元素的预测143. 2.2针铁矿法除铁142. 2.3氟化钠除钙镁153. 2.4过硫酸铁除镒154. 2.5元素的测定方法155. 2.6银的回收原理162.3172.3.1机械破碎172.3.2最正确溶解条件172.3.2银浸出率的测定172.3.3分析方法172.3.4银钻的碱沉淀回收183结果与讨论223.1 正极各元素的标准曲线错误！未定义书签.3.2 对酸的种类做初步鉴定223.2.1 酸浸原理错误！未定义书签.3. 2.2酸种类确实定错误！未定义书签.3.3 正交实验的设计263. 3.1分析各因素对银浸出率的影响294. 3.2最优条件下镇的浸出率实验343.4 银素的回收提纯343. 4.1银、钻的氧化沉淀和碱沉淀别离364. 4.2沉淀方法的选取375. 4.3PH值确实定386. 4.4PH
