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1、2024届高三化学二轮复习之微专题系列1oin1.nZ一一,、侬破险rYZnZHCNQ1.2. CH3CH2OH-h-CH3CH-WVUHN.NH,Q1./VgNJNHxNNXZCH3CH2OH、cdfwv1H浓琉球CH3CU1JC2H5微专题3-1合成路径书写专项训练(1)答案i.(丫NaIIC(K)CHii.HH().YnNaOH,HtOrV)_Br_M)l3. ClsNaoH醇溶液4. I*9Pa5. 小小0(6)CH3CHO-IaU11n:U入MgBrC2)H2OH*1C:6.00HNaClO4fs=0NaBH4OHCH1ONa/1h一0CHOCHO0CHz=CHCHO人定条件一人催化
2、剂1.JUOH00IIIH3C-CH-CH2-C-CH33H3C-CH=CH-C-CH3OH产OH1,NiC2H5(XX3CH2CH2C2H5CXCH2CH21ch2ch2cxxxh5/CH2CH2CX)OC2H5OOHKSziHNiOHOHC2HQNa)CH3COOC2H5dmf1.、.ICH3cclQ31PdCl2(PPh3)2CuIOC(X)NaCH溶液CuJlZXcINaHQlOIC(X)NaotoJ10.出赛与驾NH11.O八0C人、A1.A()H0“QohCH1COOH、OCH3CH2CH2Br,0jlxCH3NaIINHj1QNHl0ToCHOAcOHZ(CH2)5NHO12.O
3、HO17.IOH18.19.H2QlCACH2=CH2COOC2HSK2CO5PhCH2OOHCOoC、HS.-5CH3CH2COOC2H5COOGH$PhCHQa5PhCH2CICOOCSH5CH3CH2ClCMNH2、CH2CH2OHHNUYH3NH3%分HNlCH2CH2OHh3c-nn-ch2ch3OH-三l*BrBrNCCN-HCCOOH屿微专题3-3合成路径书写专项训练(3)答案1.CIuHGH(IUHolOUHIINaNH,CH【“HJ,卜*cmikhcc3h暮云逆)H2C=CH2Br2CCI4-BrBrNaOHZH2OAHOOH(7)CH3CH2CH2OH20.BrBrIIC*H,CH2CHX,H()CH3催化剂CH1CH1CHOCH3CH2CHO.7,“,二独小CH1CH2CH=CCHoWNaOH溶液/CH3BrBrIIZnCHVHzCH-C-C(X)HCH3CH2CH=CXX)!I(3分CH3CH3COOH